All countries
| 38. Round | Villarreal | Atl. Madrid | 5:1 (4:1, 1:0) | details | 24.05.2026 | |||
| 37. Round | Rayo Vallecano | Villarreal | 2:0 (1:0, 1:0) | details | 17.05.2026 | |||
| 36. Round | Villarreal | Sevilla | 2:3 (2:2, 0:1) | details | 13.05.2026 | |||
| 35. Round | Mallorca | Villarreal | 1:1 (1:1, 0:0) | details | 10.05.2026 | |||
| 34. Round | Villarreal | Levante | 5:1 (1:0, 4:1) | details | 02.05.2026 | |||
| 32. Round | Villarreal | Celta Vigo | 2:1 (2:0, 0:1) | details | 26.04.2026 | |||
| 33. Round | Oviedo | Villarreal | 1:1 (0:1, 1:0) | details | 23.04.2026 | |||
| 31. Round | Ath Bilbao | Villarreal | 1:2 (0:2, 1:0) | details | 12.04.2026 | |||
| 30. Round | Girona | Villarreal | 1:0 (1:0, 0:0) | details | 06.04.2026 | |||
| 29. Round | Villarreal | Real Sociedad | 3:1 (3:0, 0:1) | details | 20.03.2026 | |||
| 28. Round | Alaves | Villarreal | 1:1 (1:0, 0:1) | details | 13.03.2026 | |||
| 27. Round | Villarreal | Elche | 2:1 (2:0, 0:1) | details | 08.03.2026 | |||
| 26. Round | Barcelona | Villarreal | 4:1 (2:0, 2:1) | details | 28.02.2026 | |||
| 25. Round | Villarreal | Valencia | 2:1 (2:1, 0:0) | details | 22.02.2026 | |||
| 16. Round | Levante | Villarreal | 0:1 (0:0, 0:1) | details | 18.02.2026 | |||
| 24. Round | Getafe | Villarreal | 2:1 (1:0, 1:1) | details | 14.02.2026 | |||
| 23. Round | Villarreal | Espanyol | 4:1 (2:0, 2:1) | details | 09.02.2026 | |||
| 22. Round | Osasuna | Villarreal | 2:2 (2:1, 0:1) | details | 31.01.2026 | |||
| 8. Round | Bayer Leverkusen | Villarreal | 3:0 (2:0, 1:0) | details | 28.01.2026 | |||
| 21. Round | Villarreal | Real Madrid | 0:2 (0:0, 0:2) | details | 24.01.2026 | |||
| 7. Round | Villarreal | Ajax | 1:2 (0:0, 1:2) | details | 20.01.2026 | |||
| 20. Round | Betis | Villarreal | 2:0 (0:0, 2:0) | details | 17.01.2026 | |||
| 19. Round | Villarreal | Alaves | 3:1 (0:0, 3:1) | details | 10.01.2026 | |||
| 18. Round | Elche | Villarreal | 1:3 (1:2, 0:1) | details | 03.01.2026 | |||
| 17. Round | Villarreal | Barcelona | 0:2 (0:1, 0:1) | details | 21.12.2025 | |||
| 1/16-finals | Racing Santander | Villarreal | 2:1 (2:0, 0:1) | details | 17.12.2025 | |||
| 6. Round | Villarreal | FC Copenhagen | 2:3 (0:1, 2:2) | details | 10.12.2025 | |||
| 15. Round | Villarreal | Getafe | 2:0 (1:0, 1:0) | details | 06.12.2025 | |||
| 1/32-finals | Antoniano | Villarreal | 1:2 AfP (0:0, 0:0, 1:1, 3:5) | details | 03.12.2025 | |||
| 14. Round | Real Sociedad | Villarreal | 2:3 (0:1, 2:2) | details | 30.11.2025 | |||
| 5. Round | Dortmund | Villarreal | 4:0 (1:0, 3:0) | details | 25.11.2025 | |||
| 13. Round | Villarreal | Mallorca | 2:1 (1:1, 1:0) | details | 22.11.2025 | |||
| 12. Round | Espanyol | Villarreal | 0:2 (0:1, 0:1) | details | 08.11.2025 | |||
| 4. Round | Pafos | Villarreal | 1:0 (0:0, 1:0) | details | 05.11.2025 | |||
| 11. Round | Villarreal | Rayo Vallecano | 4:0 (1:0, 3:0) | details | 01.11.2025 | |||
| 1/64-finals | Ciudad de Lucena | Villarreal | 0:6 (0:2, 0:4) | details | 29.10.2025 | |||
| 10. Round | Valencia | Villarreal | 0:2 (0:1, 0:1) | details | 25.10.2025 | |||
| 3. Round | Villarreal | Manchester City | 0:2 (0:2, 0:0) | details | 21.10.2025 | |||
| 9. Round | Villarreal | Betis | 2:2 (1:0, 1:2) | details | 18.10.2025 | |||
| 8. Round | Real Madrid | Villarreal | 3:1 (0:0, 3:1) | details | 04.10.2025 | |||
| 2. Round | Villarreal | Juventus | 2:2 (1:0, 1:2) | details | 01.10.2025 | |||
| 7. Round | Villarreal | Ath Bilbao | 1:0 (0:0, 1:0) | details | 27.09.2025 | |||
| 6. Round | Sevilla | Villarreal | 1:2 (0:1, 1:1) | details | 23.09.2025 | |||
| 5. Round | Villarreal | Osasuna | 2:1 (0:1, 2:0) | details | 20.09.2025 | |||
| 1. Round | Tottenham | Villarreal | 1:0 (1:0, 0:0) | details | 16.09.2025 | |||
| 4. Round | Atl. Madrid | Villarreal | 2:0 (1:0, 1:0) | details | 13.09.2025 | |||
| 3. Round | Celta Vigo | Villarreal | 1:1 (0:0, 1:1) | details | 31.08.2025 | |||
| 2. Round | Villarreal | Girona | 5:0 (4:0, 1:0) | details | 24.08.2025 | |||
| 1. Round | Villarreal | Oviedo | 2:0 (2:0, 0:0) | details | 15.08.2025 | |||
| Villarreal | Aston Villa | 0:2 (0:1, 0:1) | details | 10.08.2025 | ||||